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Tang, Q.T., Wu, C.M., Qiao, R., Chen, Y.T. and Yang, Y.H. (2011) Catalytic Performances of Mn-Ni Mixed Hydroxide Catalysts in Liquid-Phase Benzyl Alcohol Oxidation Using Molecular Oxygen. Applied Catalysis A: General, 403, 136-141.

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• TITLE: Efficiency of Iron Supported on Porous Material (Prepared from Peanut Shell) for Liquid Phase Aerobic Oxidation of Alcohols

  AUTHORS: Mohammad Sadiq, Razia  , Sajid Hussain, Gul Zamin

  KEYWORDS: Oxidation; Iron Oxide; Activated Carbon; Alcohol; Liquid Phase

  JOURNAL NAME: Modern Research in Catalysis, Vol.3 No.2, March 28, 2014

  ABSTRACT: Catalytic activity and selectivity of prepared catalysts (Fe2O3/ and Fe2O3/AC(KOH)) were investigated for liquid phase aerobic oxidation of primary and secondary alcohols, in a batch reactor, using solvent free condition and/or eco-friendly solvents. The catalysts were characterized by SEM, EDX, XRD, FTIR, TGA/DTA, and surface area and pore size analysis. Experimental data revealed that Fe2O3/AC(KOH) was an efficient catalyst for the oxidation (dehydrogenation) of alcohol while was found to show catalytic activity for both dehydration and dehydrogenation of alcohols. The catalysts were recycled by simple filtration, and used several times without any loss of catalytic activity.