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Wang, X.-Y., Wang, Z.-M. and Gao, S. (2008) Constructing Magnetic Molecular Solids by Employing Three-Atom Ligands as Bridges. Chemical Communications, 281-284. http://dx.doi.org/10.1039/b708122g

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• TITLE: A Novel Mixed Ligand Dinuclear Complex of Cobalt (II): Synthesis, Characterization and Magnetic Studies

  AUTHORS: Emmanuel N. Nfor, Luke L. Keenan, Justin Nenwa, Peter T. Ndifon, Romanus N. Njong, Christelle N. T. Dzesse, Offiong E. Offiong

  KEYWORDS: Dinuclear Complex; Cobalt (II) Complex; Magnetic Properties; Mixed Triazole-Malonate

  JOURNAL NAME: Crystal Structure Theory and Applications, Vol.3 No.1, March 20, 2014

  ABSTRACT: A novel dinuclear complex [Co2(atr)3(mal)2(H2O)2]·4H2O(1) (atr = 4-amino-1,2,4-triazole and mal = malonic acid) containing mixed N and O-donor atoms has been prepared and structurally characterized. The structure is made up of the symmetrically 1, 2, 4-triazole bridged [Co2(atr)3(mal)2(H2O)2] moiety and four lattice water molecules. The single crystal X-ray analysis reveals that the complex has a distorted octahedral structure. Magnetic susceptibility measurements reveals that antiferromagnetic interactions exists between the high spin Co(II) ions within the dinuclear unit.