Article citationsMore>>

F. Iwasaki, O. Onomura, K. Mishima, T. Maki and Y. Matsumura, “Catalytic Activation of Trichlorosilane for Efficient and Stereoselective Reduction of Ketones,” Tetrahedron Letters, Vol. 40, No. 42, 1999, pp. 7507-7511.
http://dx.doi.org/10.1016/S0040-4039(99)01554-3

has been cited by the following article:

• TITLE: Recyclable Cyclohexanediamine Derivatives as Organocatalysts: Organocatalytic Reduction with Trichlorosilane and Aldol Reaction

  AUTHORS: Yuya Tanimura, Kaori Ishimaru

  KEYWORDS: Aldol Reaction; Cyclohexanediamine; Organocatalysis; Recyclable; Reduction

  JOURNAL NAME: International Journal of Organic Chemistry, Vol.3 No.4, December 27, 2013

  ABSTRACT: Reduction of ketimine with trichlorosilane was carried out using bisformamide catalyst 1a derived from cyclohexanediamine to give the corresponding product in 81% yield with 39% ee. Deprotection of the formyl groups of the catalysts 1 gave the corresponding diamines 2 which were utilized in aldol reaction of acetone with 4-nitrobenzaldehyde. The reaction using 2b in brine afforded the aldol adduct in 81% yield with 29% ee.