Article citationsMore>>

K. Ishimaru, K. Ono, Y. Tanimura and T. Kojima, “Novel chiral Bisformamide-Promoted Asymmetric Allylation of Benzaldehyde with Allyltrichlorosilane,” Synthetic Communications, Vol. 41, No. 24, 2011, pp. 3627-3634.
http://dx.doi.org/10.1080/00397911.2010.519841

has been cited by the following article:

• TITLE: Recyclable Cyclohexanediamine Derivatives as Organocatalysts: Organocatalytic Reduction with Trichlorosilane and Aldol Reaction

  AUTHORS: Yuya Tanimura, Kaori Ishimaru

  KEYWORDS: Aldol Reaction; Cyclohexanediamine; Organocatalysis; Recyclable; Reduction

  JOURNAL NAME: International Journal of Organic Chemistry, Vol.3 No.4, December 27, 2013

  ABSTRACT: Reduction of ketimine with trichlorosilane was carried out using bisformamide catalyst 1a derived from cyclohexanediamine to give the corresponding product in 81% yield with 39% ee. Deprotection of the formyl groups of the catalysts 1 gave the corresponding diamines 2 which were utilized in aldol reaction of acetone with 4-nitrobenzaldehyde. The reaction using 2b in brine afforded the aldol adduct in 81% yield with 29% ee.