Organic Superbase-Catalyzed Aldol Type Reactions
Guangfen Du, Fang Zhang
(2024)
Organic Superbase-Catalyzed Aldol Type Reactions: pp.
1-50.
Chapter 1. Organic superbase catalyzed vinylogous aldol reaction of carbonyl compounds
The following sections are included:
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1. N-Heterocyclic carbene catalyzed vinylogous aldol reaction of
2-(trimethylsilyloxy)furan and aldehydes
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2. N-Heterocyclic carbene-catalysed vinylogous Mukaiyama aldol
reaction of α-ketoesters and α-trifluoromethyl ketones
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3. Diastereoselective synthesis of γ-butenolides catalyzed by
potassium tert-butoxide
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4. N-Heterocyclic carbene-catalyzed fluorinated silyl-Reformatsky
reaction of aldehydes and difluoro (trimethylsilyl) acetate
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5. N-Heterocyclic carbene mediated Reformatsky reaction of
aldehydes with α-trimethylsilylcarbonyl compounds